Pyrenees Mountains. Photo: chaossart via Adobe Stock.
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Western Pyrenees foothills – the hotspot for natural hydrogen

Play-based approach of exploration opportunities and challenges in the Mauléon Basin, France

The growing interest in hydrogen within the con­text of the energy transition has recently led to renewed scientific attention, resulting in the identification of numerous natural occurrences across a wide range of geological settings.

Academic studies have signifi­cantly improved the understanding of hydrogen generation mechanisms, in particular, water-rock interactions in continental environments. These advances suggested that significant quantities of hydrogen may be gen­erated and trapped. It has led to the emergence of an exploration sec­tor dedicated to natural hydrogen resources.

In April 2022, natural hydro­gen was incorporated into the Min­ing Code in France. 45-8 ENERGY (associated with STORENGY) and TERRENSIS have already been granted exploration licenses in the south-west of the country, illustrat­ing the growing momentum toward assessing native hydrogen as an eco­nomically viable energy sector.

Reservoirs, seals and trap mechanisms evidenced from legacy hydrocarbons exploration data. Source: 45-8 ENERGY.

Why the Western Pyrenees?

The Mauléon Basin, located along the western edge of the French Pyrenees, has recently emerged as a promising area for natural hydrogen exploration. This interest is supported both by sus­tained academic research, which has identified the key components of a regional hydrogen system, and by the extensive dataset inherited from a century of oil and gas exploration.

Large-scale passive seismic ac­quisition (Maupasacq, 2018), the re­interpretation of legacy geophysical data and documented shallow hy­drogen occurrences collectively indi­cate the presence of an active hydro­gen-generating system. This system is interpreted to be associated with serpentinisation processes affecting mantle-derived rocks beneath a struc­turally complex sedimentary basin, offering favourable conditions for hy­drogen generation and potential sub­surface accumulation.

A play-based approach

Source rock – the presence of a large gravity anomaly, the “Labourd Anomaly,” in the Mauléon Basin has been recognised for several decades. Recent reinterpretations, support­ed by passive seismic data derived from local earthquake tomogra­phy, have imaged an approximately 300 km² wide high-Vp body (~8 km/s), interpreted as fresh mantle material. This relatively shallow mantle occur­rence (~8-10 km depth) is thought to have been exhumed during the Cretaceous basin hyperextension and subsequently incorporated into the orogenic wedge during the Tertiary Pyrenean compression.

Recent academic studies, based on gravity and magnetic modelling, further suggest the presence of par­tially serpentinised mantle rocks within this body, indicating ongoing hydrogen generation. Meteoric wa­ters are inferred to circulate at depth through active hydrothermal systems, as evidenced by microseismic activi­ty and the numerous thermal springs located along the northern edge of the mountain belt. Fluid circulation is likely to be facilitated by several major south-dipping frontal thrust faults, which could serve as efficient migration pathways from the crust into the overlying deformed sedimen­tary cover.

Reservoirs and Seals – extensive legacy oil and gas exploration data, primarily acquired in the Arzacq Basin during the 1960s and 1980s, have demonstrated the presence and effectiveness of regionally extensive reservoir-seal systems in Aptian-Al­bian high-porosity reefal carbonates and Barremian-Upper Jurassic high­ly permeable fractured platform car­bonates. Deeper, more speculative exploration targets have also been identified beneath the evaporitic Tri­assic-Lias sequence. Many of these formations are further documented by numerous outcrops in the inter­nal zones, particularly within the Chaînons Béarnais. In the nearby Lacq gas field, the presence of a large gas column has generated signifi­cant overpressure, providing a clear demonstration of the exceptional sealing capabilities.

Migration, trapping & preser­vation – natural hydrogen generat­ed at depth can migrate upward or laterally toward targeted reservoirs through the well-developed Pyrene­an fault system, within favourable structures such as faulted anticlines, efficiently focusing migration into effective traps. The optimal target depth for hydrogen preservation – minimising microbial activity – is over 2 km.

H2 generative system of regional extension, evidenced by new research studies based on geophysical and geochemical data acquisition. Source: 45-8 ENERGY.

Exploration target identification

Ongoing efforts by both operators aim to characterise the structural configuration of the natural hydro­gen exploration area. This work in­volves retrieving and reprocessing legacy 2D and 3D seismic data, inte­grating it with recent passive seismic acquisitions specifically designed to image hydrogen targets, and reinter­preting historical well data to better constrain the lateral extent of key res­ervoir and sealing formations identi­fied in the petroleum system.

In 2024, Terrensis conducted a dense hybrid passive seismic survey (450 sensors over four months) to generate a high-resolution Vp model for future seismic planning and estab­lish a baseline for local microseismici­ty. The resulting tomographic models significantly aided the reprocessing of vintage 2D seismic data, particular­ly due to the strong velocity contrast between the Upper Jurassic reservoir interval and its overburden. A similar survey is planned for late 2026 over the Grand Rieu license.

These integrated datasets will support the development of a consist­ent regional geological model of the Mauléon Basin. Depending on the outcomes of these investigations, fu­ture active seismic acquisitions may be required to further mature explo­ration leads already identified within the basin.

Ideal location for offtake

The Mauléon Basin has a unique set of exports route available for local markets, paving the way of the transi­tion to a local carbon-free energy.

Several possible offtake path­ways have already been identified. The region’s strong transport infra­structure supports hydrogen dis­tribution for mobility applications. Existing natural gas infrastructure can accommodate hydrogen blends of up to 10 %, enabling integration into the domestic gas network and access to future cross-border hy­drogen networks. Possible future demand potential could also arise from the opening of major industrial facilities nearby.

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